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New Colours for Carotenoids – Synthesis of Pyran Polyenes

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In memory of Professor Dr. Hans-Dieter Martin
A new type of carotenoid has been synthesized with a 2H­-pyran ring placed in the polyene chain. This compound was successively elongated by Wittig reactions. The pyran-carot­enoids obtained show a significant increased λmax compared with carotenoids lacking the pyran ring. A further remark­able bathochromic shift was observed upon protonation to pyranium-carotenoids. The pyranium ring is the distinctive feature of anthocyanidin dyes and has now become an in­ternal part of carotenoids. Eur. J. Chem. 2010, 435 – 439.
http://www3.interscience.wiley.com/cgi-bin/fulltext/123209416/PDFSTART

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